It already sounds like you're well on your way to making Pearl off-road worthy and I hope that you can make it to Moab this year because it would be great to meet both you and Pearl.
1) I'm not 100% sure what is compatible with the Trooper so hopefully others who have more experience with this will chime in. I do think that the front half shafts are compatible with the VX so I would grab those for sure. It sounds like, from another thread, the ABS module is compatible and many of ours have gone out (turning on the ABS light on the dash) so maybe grab that. I THINK the transmission and transfer case may be compatible with the VX and the engine may be compatible too. If the Trooper is a 3.2L the engine will drop right into the VX, but will have less power then the 3.5L.
2) I think that the stock Trooper rims will fit on a VX. I think some here have used Trooper rims on their VX.
3) The skid plates from a Trooper will fit on the VX. There is one that covers the transmission, one that covers the transfer case and a third that I can't remember what it covers. There are/where a couple of companies that made sliders for the VX, but I think one of them stopped making them. Hopefully someone with sliders will chime in.
4) You can definitely use your hand brake to "lock up" the rear diff when wheeling. Just pull up a couple of clicks on the hand brake lever and it does wonders. I use this trick at least one each year in Moab.
5) There really isn't anything unique that you'll need for the VX. Unless you have sliders you won't be able to use a high lift jack because we don't have any lift points on the VX.
Hope to meet you in May.
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